Document Detail

Diverse Reactions of PhI(OTf)(2) with Common 2-Electron Ligands: Complex Formation, Oxidation, and Oxidative Coupling.
MedLine Citation:
PMID:  23148595     Owner:  NLM     Status:  Publisher    
The crystal structures of bis-pyridine stabilized iodine dications [PhI(pyr)(2)](2+) are reported as triflate salts, representing the first ligand supported iodine dications to be structurally characterized. The pyridine complexes are susceptible to ligand exchange in reaction with stronger N-based donors such as 4-dimethylaminopyridine. Attempts to extend this reactivity to N-heterocyclic carbene and phosphine ligands, as has been accomplished in the earlier p-block groups, resulted in redox chemistry, with oxidation of the ligands rather than coordination.
Thomas P Pell; Shannon A Couchman; Sara Ibrahim; David J D Wilson; Brian J Smith; Peter J Barnard; Jason L Dutton
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-13
Journal Detail:
Title:  Inorganic chemistry     Volume:  -     ISSN:  1520-510X     ISO Abbreviation:  Inorg Chem     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Department of Chemistry, La Trobe Institute for Molecular Science, La Trobe University , Melbourne, Victoria, Australia 3086.
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