Document Detail


Directly Observed Halocarbene-Halocarbanion Equilibration.
MedLine Citation:
PMID:  23051027     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Equilibria between phenylhalocarbenes, halide ions, and phenyldihalomethide carbanions have been spectroscopically characterized and computationally investigated for the halogens Cl and Br. Equilibrium constants, forward and reverse rate constants, and associated thermodynamic parameters are reported.
Authors:
Lei Wang; Robert A Moss; Karsten Krogh-Jespersen
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-11
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-11     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry & Chemical Biology, Rutgers, The State University of New Jersey , New Brunswick, New Jersey 08903, United States.
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