Document Detail


Directed nucleation of monomeric and dimeric uranium(vi) complexes with a room temperature carboxyl-functionalized phosphonium ionic liquid.
MedLine Citation:
PMID:  23296265     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The carboxyl-functionalized phosphonium ionic liquid (IL), [HCTMP][Tf(2)N], enabled the directed nucleation of monomeric or dimeric uranyl(vi) compounds. This new IL is the first carboxyl-functionalized IL which is liquid at room temperature and exhibits a wider electrochemical window and lower melting point than its ammonium analogue.
Authors:
Xiao-Yan Chen; George S Goff; Mauricio Quiroz-Guzman; Daniel P Fagnant; Joan F Brennecke; Brian L Scott; Wolfgang Runde
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-8
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA. georgeg@lanl.gov.
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