Document Detail


Direct Transformation of N,N'-Methylene Bisacrylamide Self-Assembled Fibers Into Polymer Microtubes via RAFT Polymerization.
MedLine Citation:
PMID:  23139197     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A novel fabrication method of polymer tubes with simple operation process and high yield is presented. N,N'-methylene bisacrylamide (MBA) polymer microtubes are fabricated via reversible addition-fragmentation chain transfer (RAFT) polymerization using MBA self-assembled fibers as both the template and monomer source. The resulting products are characterized by SEM, TEM, FTIR, and element analysis. The mechanical properties of the gel-like product and the MBA organogel are measured by rheometer. The morphology of the polymer tubes obtained via RAFT polymerization is compared with the sample obtained via conventional radical polymerization. Based on the current investigations, the fabrication mechanism of this method is initially proposed.
Authors:
Qi Li; Liming Tang; Yu Xia; Botian Li
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-9
Journal Detail:
Title:  Macromolecular rapid communications     Volume:  -     ISSN:  1521-3927     ISO Abbreviation:  Macromol Rapid Commun     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-9     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9888239     Medline TA:  Macromol Rapid Commun     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Laboratory of Advanced materials, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P. R. China.
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