Document Detail


Direct Pd-Catalyzed Cross-Coupling of Functionalized Organoaluminum Reagents.
MedLine Citation:
PMID:  23037856     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A handsome couple: Through the use of the simple Pd catalyst [Pd(tmpp)(2) Cl(2) ] (tmpp=tris(2,4,6-trimethoxyphenyl)phosphine) and THF/DMF as solvent, various aryl-, heteroaryl-, benzyl- and alkylaluminum reagents can be readily cross-coupled with aryl or heteroaryl iodides, bromides, and nonaflates, and in special cases even with chlorides and triflates. This cross-coupling tolerates free NH(2) groups, aldehydes, ketones, esters, and nitro functions.
Authors:
Klaus Groll; Tobias D Blümke; Andreas Unsinn; Diana Haas; Paul Knochel
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-4
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-5     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department Chemie, Ludwig Maximilians-Universität München, Butenandtstrasse 5-13, Haus F, 81377 München (Germany).
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