| Direct Pd-Catalyzed Cross-Coupling of Functionalized Organoaluminum Reagents. | |
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MedLine Citation:
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PMID: 23037856 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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A handsome couple: Through the use of the simple Pd catalyst [Pd(tmpp)(2) Cl(2) ] (tmpp=tris(2,4,6-trimethoxyphenyl)phosphine) and THF/DMF as solvent, various aryl-, heteroaryl-, benzyl- and alkylaluminum reagents can be readily cross-coupled with aryl or heteroaryl iodides, bromides, and nonaflates, and in special cases even with chlorides and triflates. This cross-coupling tolerates free NH(2) groups, aldehydes, ketones, esters, and nitro functions. |
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Authors:
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Klaus Groll; Tobias D Blümke; Andreas Unsinn; Diana Haas; Paul Knochel |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-4 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-5 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Department Chemie, Ludwig Maximilians-Universität München, Butenandtstrasse 5-13, Haus F, 81377 München (Germany). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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