Document Detail


Direct Glycosylation of Unprotected and Unactivated Carbohydrates under Mild Conditions.
MedLine Citation:
PMID:  22263888     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Ligand exchange acetalization of acetals in the presence of catalytic amounts of mandelic acid and titanium tert-butoxide is reported. This transformation is successfully extended to glycosylation of unprotected and unactivated pentoses. Even unreactive pentoses such as d-arabinose or d-lyxose can be transformed by this new methodology into corresponding isopropyl glycosides.
Authors:
Matthias Pfaffe; Rainer Mahrwald
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-1-20
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2012 Jan 
Date Detail:
Created Date:  2012-1-23     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institute of Chemistry, Humboldt-University, Brook-Taylor Str. 2, 12489 Berlin, Germany.
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