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Direct Atomic-Resolution Observation of Two Phases in the Li1.2 Mn0.567 Ni0.166 Co0.067 O2 Cathode Material for Lithium-Ion Batteries.
MedLine Citation:
PMID:  23616487     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
About phase: The coexistence of rhombohedral LiTMO2 (TM=Ni, Co, or Mn) and monoclinic Li2 MnO3 -like structures inside Li1.2 Mn0.567 Ni0.166 Co0.067 O2 is revealed directly at atomic resolution. The hetero-interface along the [001]rh /[103]mon zone axis direction is demonstrated, indicating the two-phase nature of these lithium-rich cathode materials (green Li, blue Mn, red O, cyan TM).
Authors:
Haijun Yu; Ryo Ishikawa; Yeong-Gi So; Naoya Shibata; Tetsuichi Kudo; Haoshen Zhou; Yuichi Ikuhara
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-4-24
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2013 Apr 
Date Detail:
Created Date:  2013-4-25     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Umezono 1-1-1, Tsukuba, 305-8568 (Japan).
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