| Diols and anions can control the formation of an exciplex between a pyridinium boronic acid with an aryl group connected via a propylene linker. | |
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MedLine Citation:
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PMID: 20922258 Owner: NLM Status: In-Process |
Abstract/OtherAbstract:
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The exciplex formation between a pyridinium boronic acid and phenyl group connected via a propylene linker can be monitored using fluorescence. Addition of pinacol affords a cyclic boronate ester with enhanced Lewis acidity that increases the strength of its cation-π stacking interaction causing a four-fold fluorescence enhancement. |
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Authors:
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Yan-Jun Huang; Yun-Bao Jiang; Steven D Bull; John S Fossey; Tony D James |
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Publication Detail:
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Type: Journal Article Date: 2010-10-05 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: 46 ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2010 Nov |
Date Detail:
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Created Date: 2010-10-27 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: England |
Other Details:
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Languages: eng Pagination: 8180-2 Citation Subset: - |
Affiliation:
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Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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