| Dibromido[1,1'-dibenzyl-2,2'-(sulfane-diyl-dimethyl-ene)di-1H-benzimidazole]-cadmium(II) dimethyl-formamide solvate. | |
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MedLine Citation:
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PMID: 21588213 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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In the title compound, [CdBr(2)(C(30)H(26)N(4)S)]·C(3)H(7)NO, both the complex and solvent mol-ecule lie on a crystallographic mirror plane. The Cd(II) ion is coordinated in a disorted square-pyramidal CdBr(2)N(2)S environment with one of the Br atoms in the apical site. In the crystal structure, the benzimidazole ring systems are involved in weak inter-molecular π-π stacking inter-actions [centroid-centroid distances = 3.606 (2) and 3.753 (2) Å]. Further stabilization is provided by weak inter-molecular C-H⋯O hydrogen bonds. The methyl H atoms of the dimethyl-formamide solvent mol-ecule are disordered about a mirror plane. |
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Authors:
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Kaitong Wang; Jingkun Yuan; Guisheng Chen; Qian Chen; Huilu Wu |
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Publication Detail:
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Type: Journal Article Date: 2010-07-21 |
Journal Detail:
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Title: Acta crystallographica. Section E, Structure reports online Volume: 66 ISSN: 1600-5368 ISO Abbreviation: Acta Crystallogr Sect E Struct Rep Online Publication Date: 2010 |
Date Detail:
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Created Date: 2011-05-18 Completed Date: 2011-07-14 Revised Date: 2011-12-09 |
Medline Journal Info:
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Nlm Unique ID: 101089178 Medline TA: Acta Crystallogr Sect E Struct Rep Online Country: England |
Other Details:
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Languages: eng Pagination: m993 Citation Subset: - |
Affiliation:
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School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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