Document Detail


Diazido-(2,2'-bipyrid-yl)dimethanol-nickel(II).
MedLine Citation:
PMID:  21588795     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octa-hedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hy-droxy groups form intra-molecular O-H⋯(N,N) hydrogen bonds with the azide ligands.
Authors:
Hong-Gang Li; Shao-Ying Li; Li-Jun Shao
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Publication Detail:
Type:  Journal Article     Date:  2010-10-02
Journal Detail:
Title:  Acta crystallographica. Section E, Structure reports online     Volume:  66     ISSN:  1600-5368     ISO Abbreviation:  Acta Crystallogr Sect E Struct Rep Online     Publication Date:  2010  
Date Detail:
Created Date:  2011-05-18     Completed Date:  2011-07-14     Revised Date:  2013-03-29    
Medline Journal Info:
Nlm Unique ID:  101089178     Medline TA:  Acta Crystallogr Sect E Struct Rep Online     Country:  England    
Other Details:
Languages:  eng     Pagination:  m1349     Citation Subset:  -    
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