| Diastereoselective hydrophosphonylation of imines using (R,R)-TADDOL phosphite. Asymmetric synthesis of alpha-aminophosphonic acid derivatives. | |
| | |
MedLine Citation:
|
PMID: 20672154 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
|
Efficient synthesis of alpha-aminophosphonic acid derivatives is achieved, the key step being a diastereoselective hydrophosphonylation of N-diphenylphosphinyl imines using a readily available chiral cyclic (R,R)-TADDOL-phosphite derived from inexpensive natural tartaric acid. |
| | |
Authors:
|
Francisco Palacios; Tomasz K Olszewski; Javier Vicario |
Related Documents
:
|
15280054 - Accessibility of n-acyl-d-mannosamines to n-acetyl-d-neuraminic acid aldolase. 14600384 - Synthesis and antiviral activities of some 4,4'-dihydroxytriphenylmethanes. 2381974 - Synthesis of some new hydrazide-hydrazones, thiosemicarbazides, thiadiazoles, triazoles... 15624984 - Synthesis and characterization of 9-(cycloheptatrienylidene)fluorene derivatives: acid-... 15081004 - Betulinic acid and its derivatives as anti-angiogenic agents. 9590594 - In vitro effect of ascorbic acid on the proliferation of bovine scleral and tenon's cap... |
Publication Detail:
|
Type: Journal Article; Research Support, Non-U.S. Gov't Date: 2010-07-29 |
Journal Detail:
|
Title: Organic & biomolecular chemistry Volume: 8 ISSN: 1477-0539 ISO Abbreviation: Org. Biomol. Chem. Publication Date: 2010 Oct |
Date Detail:
|
Created Date: 2010-09-08 Completed Date: 2011-01-13 Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 101154995 Medline TA: Org Biomol Chem Country: England |
Other Details:
|
Languages: eng Pagination: 4255-8 Citation Subset: IM |
Affiliation:
|
Departamento de Química Orgánica I, Facultad de Farmacia, Universidad del País Vasco, Apartado 450, 01080 Vitoria, Spain. francisco.palacios@ehu.es |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
Imines
/
chemical synthesis,
chemistry* Molecular Structure Phosphites / chemical synthesis, chemistry* Phosphonic Acids / chemical synthesis*, chemistry Stereoisomerism Tartrates / chemical synthesis, chemistry |
| Chemical | |
Reg. No./Substance:
|
0/Imines; 0/Phosphites; 0/Phosphonic Acids; 0/Tartrates; 526-83-0/tartaric acid |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Role of the reagents consumption in the chaotic dynamics of the Belousov-Zhabotinsky oscillator in c...
Next Document: Synthesis of 5,6-dihydropyrrolo[2,1-a]isoquinolines featuring an intramolecular radical-oxidative cy...