Document Detail


Diastereomixture and racemate of myo-inositol derivatives, stronger organogelators than the corresponding homochiral isomers.
MedLine Citation:
PMID:  15128232     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Contrary to the usually accepted phenomena, an optically heterogeneous 1:1 diastereomixture of DS and LS and a racemate of LS and DR obtained, respectively, from a racemic myo-inositol derivative and (S)- and racemic O-acetylmandelic acid formed stronger organogels, especially with aromatic fluids, than those formed from homochiral isomers, DS and LS. One of the plausible reasons for the formation of the stronger diastereomeric gel is shown to be the complementary interaction of two diastereomers.
Authors:
Yutaka Watanabe; Tomomi Miyasou; Minoru Hayashi
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Organic letters     Volume:  6     ISSN:  1523-7060     ISO Abbreviation:  Org. Lett.     Publication Date:  2004 May 
Date Detail:
Created Date:  2004-05-06     Completed Date:  2005-01-04     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  1547-50     Citation Subset:  IM    
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama 790-8577, Japan. wyutaka@dpc.ehime-u.ac.jp
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MeSH Terms
Descriptor/Qualifier:
Gels / chemistry
Inositol / analogs & derivatives*,  chemistry
Molecular Structure
Stereoisomerism
Chemical
Reg. No./Substance:
0/Gels; 6917-35-7/Inositol

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