| Diastereomixture and racemate of myo-inositol derivatives, stronger organogelators than the corresponding homochiral isomers. | |
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MedLine Citation:
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PMID: 15128232 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Contrary to the usually accepted phenomena, an optically heterogeneous 1:1 diastereomixture of DS and LS and a racemate of LS and DR obtained, respectively, from a racemic myo-inositol derivative and (S)- and racemic O-acetylmandelic acid formed stronger organogels, especially with aromatic fluids, than those formed from homochiral isomers, DS and LS. One of the plausible reasons for the formation of the stronger diastereomeric gel is shown to be the complementary interaction of two diastereomers. |
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Authors:
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Yutaka Watanabe; Tomomi Miyasou; Minoru Hayashi |
Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Organic letters Volume: 6 ISSN: 1523-7060 ISO Abbreviation: Org. Lett. Publication Date: 2004 May |
Date Detail:
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Created Date: 2004-05-06 Completed Date: 2005-01-04 Revised Date: 2006-11-15 |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
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Languages: eng Pagination: 1547-50 Citation Subset: IM |
Affiliation:
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Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama 790-8577, Japan. wyutaka@dpc.ehime-u.ac.jp |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Gels
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chemistry Inositol / analogs & derivatives*, chemistry Molecular Structure Stereoisomerism |
| Chemical | |
Reg. No./Substance:
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0/Gels; 6917-35-7/Inositol |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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