Document Detail


Development of capillary gas chromatographic-mass spectrometric methodology for the simultaneous determination of ibuprofen and [ar-2H4]ibuprofen in serum: demonstration of kinetic equivalence in the beagle.
MedLine Citation:
PMID:  3745396     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A capillary gas chromatographic-mass spectrometric method for the determination of ibuprofen and tetra-deuterated ibuprofen in serum is described. Ibuprofen, [ar-2H4]ibuprofen and the internal standard, [ar-2H4,3,3,3-2H3]ibuprofen, are extracted (after acidification) from serum onto a cross-linked styrene divinyl benzene resin by an automated sample processor. After elution and evaporation of the organic phase, samples are reconstituted with solvent and analyzed without derivatization by capillary gas chromatography-mass spectrometry. This methodology was used to evaluate possible kinetic isotope effects after the coadministration of an equimolar mixture of ibuprofen and the deuterium-labeled covariant in the beagle. No significant differences in absorption or elimination were observed.
Authors:
D L Theis; G W Halstead; K A Halm
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal of chromatography     Volume:  380     ISSN:  0021-9673     ISO Abbreviation:  J. Chromatogr.     Publication Date:  1986 Jul 
Date Detail:
Created Date:  1986-10-02     Completed Date:  1986-10-02     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0427043     Medline TA:  J Chromatogr     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  77-87     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Animals
Chromatography, Gas
Dogs
Gas Chromatography-Mass Spectrometry
Ibuprofen / blood*
Kinetics
Therapeutic Equivalency
Chemical
Reg. No./Substance:
15687-27-1/Ibuprofen

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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