Document Detail


Development of 5-silylethynyl-1,3-dioxolan-4-one as a new prochiral template for asymmetric phase-transfer catalysis.
MedLine Citation:
PMID:  20830442     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Phase-transfer catalyzed asymmetric alkylation and Michael addition of 5-silylalkynyl-1,3-dioxolan-4-one were developed as a novel strategy to provide highly modular tertiary α-alkyl-α-hydroxy acids bearing an alkyne moiety.
Authors:
Takuya Hashimoto; Kazuhiro Fukumoto; Naoyuki Abe; Kazuki Sakata; Keiji Maruoka
Publication Detail:
Type:  Journal Article     Date:  2010-09-10
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  46     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2010 Oct 
Date Detail:
Created Date:  2010-10-06     Completed Date:  2011-01-31     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  7593-5     Citation Subset:  -    
Affiliation:
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, Japan.
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