Document Detail


Determination of tin in ores, iron, steel and non-ferrous alloys by atomic-absorption spectrophotometry after separation by extraction as the iodide.
MedLine Citation:
PMID:  18962714     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
A simple and moderately rapid method for determining 0.001% or more of tin in ores, concentrates and tailings, iron, steel and copper-, zinc-, aluminium-, titanium- and zirconium-base alloys is described. After sample decomposition, tin is separated from the matrix elements, except arsenic, by toluene extraction of its iodide from a 3M sulphuric acid-1.5M potassium iodide medium containing tartaric and ascorbic acids. It is finally back-extracted into a nitric-sulphuric acid solution containing hydrochloric acid to prevent the formation of an insoluble tin-arsenic compound and the resultant solution is evaporated to dryness. Tin is subsequently determined by atomic-absorption spectrophotometry in a nitrous oxide-acetylene flame, at 235.4 nm in a 10% hydrochloric-0.5% tartaric acid medium containing 250 mug of potassium per ml. Co-extracted arsenic does not interfere. Results obtained by this method are compared with those obtained spectrophotometrically with gallein after the separation of tin by iodide extraction.
Authors:
E M Donaldson
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Talanta     Volume:  27     ISSN:  0039-9140     ISO Abbreviation:  Talanta     Publication Date:  1980 Jun 
Date Detail:
Created Date:  2008-10-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2984816R     Medline TA:  Talanta     Country:  England    
Other Details:
Languages:  eng     Pagination:  499-505     Citation Subset:  -    
Affiliation:
Mineral Sciences Laboratories, Canada Centre for Mineral and Energy Technology, Department of Energy, Mines and Resources, Ottawa, Canada.
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