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Determination of small amounts of boron by radiation decomposition of chloroacetic acid solution.
MedLine Citation:
PMID:  18962508     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
For the determination of boron in the mug/g range in aqueous solution by activation analysis an indirect method is proposed, based on the liberation of chloride ions from chloroacetic acid by the primary reaction (10)B(n, alpha)(7)Li. The sample solution, to which is added 0.01-0.5M choroacetic acid, is irradiated with reactor neutrons. The concentration of the chloride ions liberated from the chloroacetic acid is directly proportional to the boron content of the irradiated sample. It is determined potentiometrically with a chloride-sensitive electrode. By this method boron contents >/= 10(-5) g can be detected with good reproducibility. Interference from other ionic species has been investigated and can be neglected. The method is suitable for the determination of boron in biological matrices.
Authors:
M H Yang; C L Tseng; G Tölg
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Talanta     Volume:  26     ISSN:  0039-9140     ISO Abbreviation:  Talanta     Publication Date:  1979 Aug 
Date Detail:
Created Date:  2008-10-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2984816R     Medline TA:  Talanta     Country:  England    
Other Details:
Languages:  eng     Pagination:  705-11     Citation Subset:  -    
Affiliation:
Institute of Nuclear Science, National Tsing Hua University, Taiwan, Republic of China.
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