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Determination of small amounts of TBP and DBP in uranyl nitrate solutions.
MedLine Citation:
PMID:  18960556     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
Tri- and dibutylphosphate (TBP and DBP) in concentrated uranyl nitrate solution are determined by a method based on the solvent extraction of zirconium-95. The distribution ratio of zirconium-95 between dilute solutions of TBP and DBP in dodecane and 10M hydrochloric acid and 1Mnitric acid respectively is measured. There is a logarithmic relationship between the distribution ratio and concentration of TBP and DBP, which enables them to be determined rapidly and with an error of +/- 10% over the range 1-100ppm of TBP and 40-600 ppm of DBP. The lower limit is 0.5 ppm for TBP and 10 ppm for DBP.
Authors:
T Ishimori; K Ueno
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Talanta     Volume:  16     ISSN:  0039-9140     ISO Abbreviation:  Talanta     Publication Date:  1969 May 
Date Detail:
Created Date:  2008-10-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2984816R     Medline TA:  Talanta     Country:  England    
Other Details:
Languages:  eng     Pagination:  613-6     Citation Subset:  -    
Affiliation:
Chemistry Division Japan Atomic Energy Research Institute Tokai, Ibaraki, Japan.
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