Document Detail


Determination of catalytic reaction mechanisms by isotopic frequency response.
MedLine Citation:
PMID:  23034591     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Efficient catalysts are of extraordinary importance for the development of efficient chemical processes as well as applications such as energy storage. Rational development of catalysts requires a mechanistic understanding of the catalytic reaction. Since steady-state investigations are insufficient to gain mechanistic understanding, transient methods such as SSITKA and frequency response have been developed. In this paper we provide a theoretical basis for a frequency response method based on variations in the isotopic composition of the reactant. This approach is particularly useful, since it permits transient investigations under quasi-steady state conditions and because the response is linear.
Authors:
Urs Hartfelder; Jakub Szlachetko; Jacinto Sá; Jeroen A van Bokhoven
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-4
Journal Detail:
Title:  The Analyst     Volume:  -     ISSN:  1364-5528     ISO Abbreviation:  Analyst     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0372652     Medline TA:  Analyst     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institute for Chemical and Bioengineering, ETH Zürich, Wolfgang-Pauli Strasse 10, 8093 Zürich, Switzerland.
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