Document Detail


Detection of unusual carotenoid esters in fresh mango (Mangifera indica L. cv. 'Kent').
MedLine Citation:
PMID:  14559275     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The carotenoid pattern of mango cv. 'Kent' was investigated by LC-(APcI)MS analyses. In solvent extracts from the mesocarp an unusual carotenoid ester was identified as violaxanthin dibutyrate. For unequivocal identification of butyric acid by an independent method, total lipids were isolated by solvent extraction from the fruit flesh and analyzed by GC after saponification and subsequent methylation. Thus, evidence of butyric acid (1.6 area%) was provided. To the best of our knowledge, this is the first report on a xanthophyll dibutyrate in plants. Additionally, further carotenoid peaks were tentatively assigned to 9-cis-violaxanthin and neochrom or luteoxanthin, respectively, by their UV/vis and MS data of the saponified extracts.
Authors:
Isabell Pott; Dietmar E Breithaupt; Reinhold Carle
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Phytochemistry     Volume:  64     ISSN:  0031-9422     ISO Abbreviation:  Phytochemistry     Publication Date:  2003 Oct 
Date Detail:
Created Date:  2003-10-15     Completed Date:  2003-12-18     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0151434     Medline TA:  Phytochemistry     Country:  United States    
Other Details:
Languages:  eng     Pagination:  825-9     Citation Subset:  IM    
Affiliation:
Institute for Agricultural Engineering in the Tropics and Subtropics, Hohenheim University, Garbenstrasse 9, D-70599 Stuttgart, Germany.
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MeSH Terms
Descriptor/Qualifier:
Butyric Acid / analysis,  chemistry
Carotenoids / chemistry*,  isolation & purification*
Chromatography, Gas
Chromatography, High Pressure Liquid / methods
Esters / chemistry,  isolation & purification
Fatty Acids / analysis
Fruit / chemistry*
Lipids / chemistry
Mangifera / chemistry*
Mass Spectrometry / methods
Pigments, Biological
Plant Extracts / chemistry
Spectrophotometry, Ultraviolet
Xanthophylls / chemistry,  isolation & purification
beta Carotene / analogs & derivatives*,  chemistry,  isolation & purification
Chemical
Reg. No./Substance:
0/Esters; 0/Fatty Acids; 0/Lipids; 0/Pigments, Biological; 0/Plant Extracts; 0/Xanthophylls; 107-92-6/Butyric Acid; 126-29-4/violaxanthin; 36-88-4/Carotenoids; 7235-40-7/beta Carotene

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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