Document Detail


Design and synthesis of stable α-diazo-β-oxo sulfoxides.
MedLine Citation:
PMID:  23377233     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Diazo transfer adjacent to a sulfoxide moiety to provide stable, isolable α-diazo-β-oxo sulfoxides has been achieved. Use of monocyclic and bicyclic sulfoxide precursors is critical in enabling isolation of stable derivatives, through introduction of conformational constraint, while acyclic α-diazo-β-oxo sulfoxides are too labile to isolate and characterize.
Authors:
Stuart G Collins; Orlagh C M O'Sullivan; Patrick G Kelleher; Anita R Maguire
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-2-4
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  -     ISSN:  1477-0539     ISO Abbreviation:  Org. Biomol. Chem.     Publication Date:  2013 Feb 
Date Detail:
Created Date:  2013-2-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, Analytical and Biological Chemistry Research Facility, University College Cork, Ireland. stuart.collins@ucc.ie.
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