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Design and synthesis of porphyrin-containing catenanes and rotaxanes.
MedLine Citation:
PMID:  19169458     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Catenanes and rotaxanes containing porphyrin subunits have become popular synthetic targets because of the large variety of available synthetic strategies including the coordination chemistry of metallated porphyrins, coupled with the many attractive physical properties of porphyrins. This tutorial review outlines various synthetic approaches and templating strategies that have been used to prepare a range of mechanically interlocked architectures that incorporate porphyrins as fundamental subunits either grafted onto macrocycles or as stoppers. These species are of interest in relation to recreating natural processes such as the photosynthetic apparatus or enzyme binding sites.
Authors:
Jonathan A Faiz; Valérie Heitz; Jean-Pierre Sauvage
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Publication Detail:
Type:  Journal Article     Date:  2008-11-24
Journal Detail:
Title:  Chemical Society reviews     Volume:  38     ISSN:  0306-0012     ISO Abbreviation:  Chem Soc Rev     Publication Date:  2009 Feb 
Date Detail:
Created Date:  2009-01-26     Completed Date:  2009-03-20     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0335405     Medline TA:  Chem Soc Rev     Country:  England    
Other Details:
Languages:  eng     Pagination:  422-42     Citation Subset:  -    
Affiliation:
Laboratoire de Chimie Organo-Minérale, LC 3, UMR 7177 du CNRS, Université Louis Pasteur, Faculté de Chimie, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France.
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