| Decatungstate-mediated radical reactions of C60 with substituted toluenes and anisoles: a new photochemical functionalization strategy for fullerenes. | |
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MedLine Citation:
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PMID: 18237181 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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A convenient, highly efficient, decatungstate-mediated chemical methodology to functionalize fullerenes is demonstrated. A variety of radicals have been generated by the photochemical interaction of tetrabutylammonium decatungstate [(n-Bu4N)4W10O32] and para-substituted toluenes, anisoles, and thioanisole and effectively trapped by the [60]fullerene affording the corresponding 1,2-dihydro[60]fullerene monoadducts in moderate to good yields. |
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Authors:
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Manolis D Tzirakis; Michael Orfanopoulos |
Publication Detail:
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Type: Journal Article Date: 2008-02-01 |
Journal Detail:
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Title: Organic letters Volume: 10 ISSN: 1523-7060 ISO Abbreviation: Org. Lett. Publication Date: 2008 Mar |
Date Detail:
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Created Date: 2008-02-28 Completed Date: 2008-05-15 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
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Languages: eng Pagination: 873-6 Citation Subset: - |
Affiliation:
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Department of Chemistry, University of Crete, 71003, Voutes - Heraklion, Crete, Greece. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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