Document Detail


Cyclopentadienylruthenium π Complexes of Subphthalocyanines: A "Drop-Pin" Approach To Modifying the Electronic Features of Aromatic Macrocycles.
MedLine Citation:
PMID:  23044649     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Facing facts: Coordination of Cp*Ru (Cp*=C(5) Me(5) ) to the concave and convex π surfaces of subphthalocyanines constitutes a new approach to the functionalization of subazaporphyrins. While the convex face shows higher reactivity, coordination to the concave side produces a stronger diatropic influence on the Cp* ligand and a greater perturbation of the macrocyclic π-electronic features.
Authors:
Esmeralda Caballero; Javier Fernández-Ariza; Vincent M Lynch; Carlos Romero-Nieto; M Salomé Rodríguez-Morgade; Jonathan L Sessler; Dirk M Guldi; Tomás Torres
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-9
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-9     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Departamento de Química Orgánica, Universidad Autónoma de Madrid, Cantoblanco, 28049-Madrid (Spain).
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