| Cyclopentadienylruthenium π Complexes of Subphthalocyanines: A "Drop-Pin" Approach To Modifying the Electronic Features of Aromatic Macrocycles. | |
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MedLine Citation:
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PMID: 23044649 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Facing facts: Coordination of Cp*Ru (Cp*=C(5) Me(5) ) to the concave and convex π surfaces of subphthalocyanines constitutes a new approach to the functionalization of subazaporphyrins. While the convex face shows higher reactivity, coordination to the concave side produces a stronger diatropic influence on the Cp* ligand and a greater perturbation of the macrocyclic π-electronic features. |
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Authors:
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Esmeralda Caballero; Javier Fernández-Ariza; Vincent M Lynch; Carlos Romero-Nieto; M Salomé Rodríguez-Morgade; Jonathan L Sessler; Dirk M Guldi; Tomás Torres |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-9 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-9 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Departamento de Química Orgánica, Universidad Autónoma de Madrid, Cantoblanco, 28049-Madrid (Spain). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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