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Cycling behaviour of Li/Li(4)Ti(5)O(12) cells studied by electrochemical impedance spectroscopy.
MedLine Citation:
PMID:  21365085     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We studied the behaviour of Li/Li(4)Ti(5)O(12) cells by electrochemical impedance spectroscopy to gain insight into the changes at the electrode/electrolyte interfaces during extensive cycling. A simple equivalent-circuit model is able to describe the impedance of the complete battery as a function of both state-of-charge and state-of-degradation. The formation of the solid-electrolyte interface and dendrite growth at the Li metal electrode have a strong influence on the impedance measurements although the battery performance is not significantly affected.
Authors:
Nina Schweikert; Horst Hahn; Sylvio Indris
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-3-1
Journal Detail:
Title:  Physical chemistry chemical physics : PCCP     Volume:  -     ISSN:  1463-9084     ISO Abbreviation:  -     Publication Date:  2011 Mar 
Date Detail:
Created Date:  2011-3-2     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100888160     Medline TA:  Phys Chem Chem Phys     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institute of Nanotechnology, Karlsruhe Institute of Technology, P.O. Box 3640, 76021 Karlsruhe, Germany. Sylvio.Indris@kit.edu.
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