| Cycling behaviour of Li/Li(4)Ti(5)O(12) cells studied by electrochemical impedance spectroscopy. | |
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MedLine Citation:
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PMID: 21365085 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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We studied the behaviour of Li/Li(4)Ti(5)O(12) cells by electrochemical impedance spectroscopy to gain insight into the changes at the electrode/electrolyte interfaces during extensive cycling. A simple equivalent-circuit model is able to describe the impedance of the complete battery as a function of both state-of-charge and state-of-degradation. The formation of the solid-electrolyte interface and dendrite growth at the Li metal electrode have a strong influence on the impedance measurements although the battery performance is not significantly affected. |
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Authors:
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Nina Schweikert; Horst Hahn; Sylvio Indris |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-3-1 |
Journal Detail:
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Title: Physical chemistry chemical physics : PCCP Volume: - ISSN: 1463-9084 ISO Abbreviation: - Publication Date: 2011 Mar |
Date Detail:
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Created Date: 2011-3-2 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100888160 Medline TA: Phys Chem Chem Phys Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Institute of Nanotechnology, Karlsruhe Institute of Technology, P.O. Box 3640, 76021 Karlsruhe, Germany. Sylvio.Indris@kit.edu. |
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