Document Detail


Cyclic alkenyl boronic half acid synthesis and applications.
MedLine Citation:
PMID:  20701318     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The synthesis of cyclic alkenyl boronic half acids from vinyl and propenyl boronic esters and homoallylic alcohols by ring-closing metathesis is reported. The method is compatible with both conventional and microwave heating and comparable yields are obtained under both conditions. The cyclic alkenyl boronic acids participate in Suzuki-Miyaura coupling reactions in good yields.
Authors:
LuAnne McNulty; Kris Kohlbacher; Katie Borin; Bryan Dodd; Jeni Bishop; Lindsey Fuller; Zach Wright
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Publication Detail:
Type:  Journal Article; Research Support, U.S. Gov't, Non-P.H.S.    
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  75     ISSN:  1520-6904     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2010 Sep 
Date Detail:
Created Date:  2010-08-27     Completed Date:  2010-12-08     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  6001-4     Citation Subset:  IM    
Affiliation:
Butler University, 4600 Sunset Avenue, Indianapolis, Indiana 46208, USA. lmcnulty@butler.edu
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MeSH Terms
Descriptor/Qualifier:
Alcohols / chemical synthesis*,  chemistry*
Boronic Acids / chemical synthesis*,  chemistry*
Cyclization
Esters / chemistry*
Microwaves
Molecular Structure
Stereoisomerism
Chemical
Reg. No./Substance:
0/Alcohols; 0/Boronic Acids; 0/Esters

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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