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Cu(OAc)2-catalyzed N-arylations of sulfoximines with aryl boronic acids.
MedLine Citation:
PMID:  15957917     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
[reaction: see text] A simple and mild copper salt-catalyzed N-arylation of sulfoximines in high yields is reported. Cu(OAc)(2) activates aryl boronic acids for the reaction with NH-sulfoximines without additional base or heating. Furthermore, this new method allows the preparation of N-arylated sulfoximines, which have previously been more difficult to access.
Authors:
Christian Moessner; Carsten Bolm
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Organic letters     Volume:  7     ISSN:  1523-7060     ISO Abbreviation:  Org. Lett.     Publication Date:  2005 Jun 
Date Detail:
Created Date:  2005-06-16     Completed Date:  2006-04-17     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  2667-9     Citation Subset:  -    
Affiliation:
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, D-52056 Aachen, Germany.
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