Document Detail


Copper-promoted N-cyclopropylation of anilines and amines by cyclopropylboronic acid.
MedLine Citation:
PMID:  20361101     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Reaction of anilines, primary and secondary aliphatic amines with cyclopropylboronic acid in dichloroethane in the presence of Cu(OAc)(2) (1 equiv.), 2,2'-bipyridine (1 equiv.) and sodium carbonate or sodium bicarbonate (2 equiv.) under air atmosphere afforded the corresponding N-cyclopropyl derivatives in good to excellent yields.
Authors:
Sébastien Bénard; Luc Neuville; Jieping Zhu
Publication Detail:
Type:  Journal Article     Date:  2010-04-01
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  46     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2010 May 
Date Detail:
Created Date:  2010-05-07     Completed Date:  2010-08-27     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  3393-5     Citation Subset:  IM    
Affiliation:
Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif-sur-Yvette, France.
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MeSH Terms
Descriptor/Qualifier:
Amines / chemistry*
Aniline Compounds / chemistry*
Boronic Acids / chemistry*
Copper / chemistry*
Cyclopropanes / chemical synthesis*,  chemistry
Molecular Structure
Organometallic Compounds / chemistry*
Stereoisomerism
Chemical
Reg. No./Substance:
0/Amines; 0/Aniline Compounds; 0/Boronic Acids; 0/Cyclopropanes; 0/Organometallic Compounds; 62-53-3/aniline; 7440-50-8/Copper

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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