| Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts. | |
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MedLine Citation:
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PMID: 21773611 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The ligand-free trifluoromethylation of arylboronic acids with a [Ph(2)SCF(3)](+)[OTf](-)/Cu(0) system has been carefully investigated. Aryl-, alkenyl- and heteroarylboronic acids with a variety of functional groups were suitable substrates for this reaction. It is suggested that a CuCF(3) species is formed under the reaction conditions. |
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Authors:
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Cheng-Pan Zhang; Ji Cai; Chang-Bing Zhou; Xiao-Ping Wang; Xing Zheng; Yu-Cheng Gu; Ji-Chang Xiao |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-7-19 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: - Publication Date: 2011 Jul |
Date Detail:
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Created Date: 2011-7-20 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. jchxiao@mail.sioc.ac.cn. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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