| Copper-Catalyzed Formic Acid Synthesis from CO(2) with Hydrosilanes and H(2)O. | |
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MedLine Citation:
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PMID: 22540994 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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A copper-catalyzed formic acid synthesis from CO(2) with hydrosilanes has been accomplished. The Cu(OAc)(2)·H(2)O-1,2-bis(diphenylphosphino)benzene system is highly effective for the formic acid synthesis under 1 atm of CO(2). The TON value approached 8100 in 6 h. The reaction pathway was revealed by in situ NMR analysis and isotopic experiments. |
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Authors:
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Ken Motokura; Daiki Kashiwame; Akimitsu Miyaji; Toshihide Baba |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-4-27 |
Journal Detail:
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Title: Organic letters Volume: - ISSN: 1523-7052 ISO Abbreviation: - Publication Date: 2012 Apr |
Date Detail:
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Created Date: 2012-4-30 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Interdisciplinary Graduate School of Science and Engineering, Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology , 4259 Nagatsuta-cho, Midori-ku, Yokohama, 226-8502, Japan. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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