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Copper-Catalyzed Formic Acid Synthesis from CO(2) with Hydrosilanes and H(2)O.
MedLine Citation:
PMID:  22540994     Owner:  NLM     Status:  Publisher    
A copper-catalyzed formic acid synthesis from CO(2) with hydrosilanes has been accomplished. The Cu(OAc)(2)·H(2)O-1,2-bis(diphenylphosphino)benzene system is highly effective for the formic acid synthesis under 1 atm of CO(2). The TON value approached 8100 in 6 h. The reaction pathway was revealed by in situ NMR analysis and isotopic experiments.
Ken Motokura; Daiki Kashiwame; Akimitsu Miyaji; Toshihide Baba
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-4-27
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2012 Apr 
Date Detail:
Created Date:  2012-4-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Interdisciplinary Graduate School of Science and Engineering, Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology , 4259 Nagatsuta-cho, Midori-ku, Yokohama, 226-8502, Japan.
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