Document Detail


Copper-Catalyzed Formic Acid Synthesis from CO(2) with Hydrosilanes and H(2)O.
MedLine Citation:
PMID:  22540994     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A copper-catalyzed formic acid synthesis from CO(2) with hydrosilanes has been accomplished. The Cu(OAc)(2)·H(2)O-1,2-bis(diphenylphosphino)benzene system is highly effective for the formic acid synthesis under 1 atm of CO(2). The TON value approached 8100 in 6 h. The reaction pathway was revealed by in situ NMR analysis and isotopic experiments.
Authors:
Ken Motokura; Daiki Kashiwame; Akimitsu Miyaji; Toshihide Baba
Related Documents :
15392564 - Quantitative cytochemical determination of desoxyribonucleic acid with the feulgen nucl...
18966844 - The reaction of glutamic acid and trinitrobenzenesulfonic acid--kinetic study and analy...
886434 - Reactions of benzenesulfonohydrazides and benzenesulfonamides with hydrogen chloride or...
240854 - Biosynthesis of cholic acid in rat liver. 24-hydroxylation of 3alpha, 7alpha, 12alpha-t...
22209864 - Synthesis of biologically stable gold nanoparticles using imidazolium-based amino acid ...
17121654 - Relationship between seminal ascorbic acid and sperm dna integrity in infertile men.
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-4-27
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2012 Apr 
Date Detail:
Created Date:  2012-4-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Interdisciplinary Graduate School of Science and Engineering, Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology , 4259 Nagatsuta-cho, Midori-ku, Yokohama, 226-8502, Japan.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  GnRH agonist versus GnRH antagonist in assisted reproduction cycles: oocyte morphology.
Next Document:  An update on treatment of onychomycosis.