| Copper-Catalyzed Difluoromethylation of β,γ-Unsaturated Carboxylic Acids: An Efficient Allylic Difluoromethylation. | |
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MedLine Citation:
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PMID: 23070804 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Not one but two! A new strategy for the regiospecific construction of compounds with allylic CF(2) H groups has been developed. The decarboxylative (phenylsulfonyl)difluoromethylation of β,γ-unsaturated carboxylic acids is catalyzed by a Lewis acid (CuCl(2) ⋅2 H(2) O), and the resulting product easily undergoes desulfonylation. |
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Authors:
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Zhengbiao He; Mingyou Hu; Tao Luo; Lingchun Li; Jinbo Hu |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-15 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-16 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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