Document Detail


Coordination driven axial chirality in a microporous solid assembled from an achiral linker via in situ C-N coupling.
MedLine Citation:
PMID:  21904744     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Metal mediated in situ C-N coupling between 4,4'-azobipyridine and disodium-trans-glutaconate at room temperature has formed a new multifunctional linker Z-dhpe which subsequently self-assembles with Zn(ii) or Cd(ii) resulting in a chiral or an achiral metal-organic framework, respectively, depending on its different coordination modes.
Authors:
Prakash Kanoo; Ritesh Haldar; Soumya T Cyriac; Tapas Kumar Maji
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-9-9
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  -     Publication Date:  2011 Sep 
Date Detail:
Created Date:  2011-9-9     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India. tmaji@jncasr.ac.in.
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