Document Detail


Coordination Chemistry at Carbon: The Patchwork Family Comprising (Ph(3) P)(2) C, (Ph(3) P)C(C(2) H(4) ), and (C(2) H(4) )(2) C.
MedLine Citation:
PMID:  23203500     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The revitalized concept of "coordination at carbon" allows relationships between seemingly unrelated families of carbon-centered compounds to be discovered generating fascinating patchwork families of compounds. It is shown how olefins and cyclopropanes can be regarded as donors for carbon acceptors C(1) , C(2) , and C(3) . Through this approach, hydrocarbons such as spiropentane and dicyclopropylidene are found to be counterparts of the bis-ylidic carbodiphosphoranes and the corresponding mixed mono-ylidic systems.
Authors:
Hubert Schmidbaur; Annette Schier
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-12-3
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Dec 
Date Detail:
Created Date:  2012-12-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department Chemie, Technische Universität München, 85747 Garching b. M. (Germany); Chemistry Department, King Abdulaziz University, Jeddah, 21589 (Saudi Arabia). H.Schmidbaur@lrz.tum.de.
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