Document Detail


Conversion of nonporous helical cadmium organic framework to a porous form.
MedLine Citation:
PMID:  20571703     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Two novel cadmium-organic frameworks containing achiral helical nanotubular channels, [Cd(HImDC)(S)](n) (S = Im(1) and Py(2)), have been synthesized and characterized using single crystal X-ray diffraction, in which 1 converts to 2 upon refluxing 1 in pyridine solution with noticeable porosity and hydrogen uptake at medium pressure.
Authors:
Zhi-Gang Gu; Yue-Peng Cai; Hua-Cai Fang; Zheng-Yuan Zhou; Praveen K Thallapally; Jian Tian; Jun Liu; Gregory J Exarhos
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Publication Detail:
Type:  Journal Article     Date:  2010-06-22
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  46     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2010 Aug 
Date Detail:
Created Date:  2010-07-15     Completed Date:  2010-10-05     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  5373-5     Citation Subset:  -    
Affiliation:
School of Chemistry and Environment, Key Lab of Technology on Electrochemical Energy Storage and Power Generation in Guangdong Universities, Engineering Research Center of Materials and Technology for Electrochemical EnergyStorage (Ministry of Education), South China Normal University, Guangzhou 510006.
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