Document Detail


Control of cytoplasmic calcium with photolabile tetracarboxylate 2-nitrobenzhydrol chelators.
MedLine Citation:
PMID:  3098316     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
This paper introduces nitr-2, a new Ca2+ chelator designed to release Ca2+ upon illumination with near UV (300-400 nm) light. Before illumination nitr-2 has Ca2+ dissociation constants of 160 and 630 nM in 0.1 and 0.3 M ionic strength respectively; after photoconversion to a nitrosobenzophenone the values shift to 7 and 18 microM, high enough to liberate substantial amounts of Ca2+ under intracellular conditions. The speed of release is limited by a dark reaction with rate constant 5 s-1. Aplysia central neurons injected with nitr-2 and exposed to UV light exhibit two separate Ca2+-dependent membrane currents: one carried by potassium ions and one a nonspecific cation current. A quantitative estimate of the spatial distribution of intracellular [Ca2+] changes in large cells filled with a high concentration of nitr-2 and exposed to an intense UV flash is offered.
Authors:
R Y Tsien; R S Zucker
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, P.H.S.    
Journal Detail:
Title:  Biophysical journal     Volume:  50     ISSN:  0006-3495     ISO Abbreviation:  Biophys. J.     Publication Date:  1986 Nov 
Date Detail:
Created Date:  1987-02-11     Completed Date:  1987-02-11     Revised Date:  2009-11-18    
Medline Journal Info:
Nlm Unique ID:  0370626     Medline TA:  Biophys J     Country:  UNITED STATES    
Other Details:
Languages:  eng     Pagination:  843-53     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Animals
Aplysia
Calcium / metabolism*
Chelating Agents / pharmacology*
Cytoplasm / metabolism
Egtazic Acid / analogs & derivatives*,  chemical synthesis,  pharmacology
Kinetics
Membrane Potentials / drug effects
Neurons / physiology
Photolysis
Grant Support
ID/Acronym/Agency:
EY-04372/EY/NEI NIH HHS; GM-31004/GM/NIGMS NIH HHS; NS-15114/NS/NINDS NIH HHS
Chemical
Reg. No./Substance:
0/Chelating Agents; 103471-64-3/nitr 2; 67-42-5/Egtazic Acid; 7440-70-2/Calcium
Comments/Corrections

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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