Document Detail

Continuous flow hydrogenation using polysilane-supported palladium/alumina hybrid catalysts.
MedLine Citation:
PMID:  21804868     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Continuous flow systems for hydrogenation using polysilane-supported palladium/alumina (Pd/(PSi-Al(2)O(3))) hybrid catalysts were developed. Our original Pd/(PSi-Al(2)O(3)) catalysts were used successfully in these systems and the hydrogenation of unsaturated C-C bonds and a nitro group, deprotection of a carbobenzyloxy (Cbz) group, and a dehalogenation reaction proceeded smoothly. The catalyst retained high activity for at least 8 h under neat conditions.
Hidekazu Oyamada; Takeshi Naito; Shū Kobayashi
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Publication Detail:
Type:  Journal Article     Date:  2011-05-31
Journal Detail:
Title:  Beilstein journal of organic chemistry     Volume:  7     ISSN:  1860-5397     ISO Abbreviation:  Beilstein J Org Chem     Publication Date:  2011  
Date Detail:
Created Date:  2011-08-01     Completed Date:  2011-11-10     Revised Date:  2013-05-29    
Medline Journal Info:
Nlm Unique ID:  101250746     Medline TA:  Beilstein J Org Chem     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  735-9     Citation Subset:  -    
Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
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