Document Detail


Continuous flow enantioselective arylation of aldehydes with ArZnEt using triarylboroxins as the ultimate source of aryl groups.
MedLine Citation:
PMID:  20126636     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
A continuous flow system for the synthesis of enantioenriched diarylmethanols from aldehydes is described. The system uses an amino alcohol-functionalized polystyrene resin as the catalyst, and the arylating agent is conveniently prepared by transmetallation of triarylboroxins with diethylzinc.
Authors:
Julien Rolland; Xacobe C Cambeiro; Carles Rodríguez-Escrich; Miquel A Pericàs
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Publication Detail:
Type:  Journal Article     Date:  2009-10-15
Journal Detail:
Title:  Beilstein journal of organic chemistry     Volume:  5     ISSN:  1860-5397     ISO Abbreviation:  Beilstein J Org Chem     Publication Date:  2009  
Date Detail:
Created Date:  2010-02-03     Completed Date:  2010-05-20     Revised Date:  2010-09-27    
Medline Journal Info:
Nlm Unique ID:  101250746     Medline TA:  Beilstein J Org Chem     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  56     Citation Subset:  -    
Affiliation:
Institute of Chemical Research of Catalonia, Avinguda Països Catalans, Tarragona, Spain.
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