Document Detail


Contact de-Electrification of Electrostatically Charged Polymers.
MedLine Citation:
PMID:  23153329     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The contact electrification of insulating organic polymers is still incompletely understood, in part because multiple fundamental mechanisms may contribute to the movement of charge. This study describes a mechanism previously unreported in the context of contact electrification: that is, "contact de-electrification", a process in which polymers charged to the same polarity discharge on contact. Both positively charged polymeric beads, e.g., polyamide 6/6 (Nylon) and polyoxymethylene (Delrin(R)), and negatively charged polymeric beads, e.g., polytetrafluoroethylene (Teflon(R)) and polyamide-imide (Torlon(R)), discharge when the like-charged beads are brought into contact. The beads (both with charges of ~±20 µC/m2, or ~100 charges/µm2) discharge on contact regardless of whether they are made of the same material, or of different materials. Discharge is rapid: discharge of flat slabs of like-charged Nylon and Teflon pieces is completed on a single contact (~3 sec). The charge lost from the polymers during contact de-electrification transfers onto molecules of gas in the atmosphere. When like-charged polymers are brought into contact, the increase in electric field at the point of contact exceeds the dielectric breakdown strength of the atmosphere and ionizes molecules of the gas; this ionization thus leads to discharge of the polymers. The detection (using a Faraday Cup) of charges transferred to the Cup by the ionized gas is compatible with the mechanism. Contact de-electrification occurs for different polymers and in atmospheres with different values of dielectric breakdown strength (helium, argon, oxygen, carbon dioxide, nitrogen, and sulfur hexafluoride): the mechanism thus appears to be general.
Authors:
Siowling Soh; Sen Wai Kwok; Helena Liu; George M Whitesides
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-15
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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