Document Detail


Confusion, inversion, and creation--a new spring from porphyrin chemistry.
MedLine Citation:
PMID:  12271617     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
This article mainly deals with the recent serendipity of novel porphyrin analogs such as N-confused porphyrin. The unique property of this ligand allows the formation of a variety of metal complexes. The important aspect of dynamic flipping (inversion), induced either by confusion or expansion of the macrocyclic core, that leads to the generation of new porphyrinoids, is emphasized. This review concludes with the recent progress on expanded porphyrins bearing confused, inverted, and fused pyrrole rings.
Authors:
Hiroyuki Furuta; Hiromitsu Maeda; Atsuhiro Osuka
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1359-7345     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2002 Sep 
Date Detail:
Created Date:  2002-09-25     Completed Date:  2003-02-25     Revised Date:  2003-11-03    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  1795-804     Citation Subset:  -    
Affiliation:
Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan. hfuruta@kuchem.kyoto-u.ac.jp
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