Document Detail


Complete biological reductive transformation of tetrachloroethene to ethane.
MedLine Citation:
PMID:  1622277     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Reductive dechlorination of tetrachloroethene (perchloroethylene; PCE) was observed at 20 degrees C in a fixed-bed column, filled with a mixture (3:1) of anaerobic sediment from the Rhine river and anaerobic granular sludge. In the presence of lactate (1 mM) as an electron donor, 9 microM PCE was dechlorinated to ethene. Ethene was further reduced to ethane. Mass balances demonstrated an almost complete conversion (95 to 98%), with no chlorinated compounds remaining (less than 0.5 micrograms/liter). When the temperature was lowered to 10 degrees C, an adaptation of 2 weeks was necessary to obtain the same performance as at 20 degrees C. Dechlorination by column material to ethene, followed by a slow ethane production, could also be achieved in batch cultures. Ethane was not formed in the presence of bromoethanesulfonic acid, an inhibitor of methanogenesis. The high dechlorination rate (3.7 mumol.l-1.h-1), even at low temperatures and considerable PCE concentrations, together with the absence of chlorinated end products, makes reductive dechlorination an attractive method for removal of PCE in bioremediation processes.
Authors:
W P de Bruin; M J Kotterman; M A Posthumus; G Schraa; A J Zehnder
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Applied and environmental microbiology     Volume:  58     ISSN:  0099-2240     ISO Abbreviation:  Appl. Environ. Microbiol.     Publication Date:  1992 Jun 
Date Detail:
Created Date:  1992-08-06     Completed Date:  1992-08-06     Revised Date:  2010-09-10    
Medline Journal Info:
Nlm Unique ID:  7605801     Medline TA:  Appl Environ Microbiol     Country:  UNITED STATES    
Other Details:
Languages:  eng     Pagination:  1996-2000     Citation Subset:  IM    
Affiliation:
Department of Microbiology, Wageningen Agricultural University, The Netherlands.
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MeSH Terms
Descriptor/Qualifier:
Ethane / pharmacokinetics
Metabolic Detoxication, Drug
Oxidation-Reduction
Tetrachloroethylene / pharmacokinetics*
Water Microbiology
Water Pollutants, Chemical / pharmacokinetics
Chemical
Reg. No./Substance:
0/Water Pollutants, Chemical; 127-18-4/Tetrachloroethylene; 74-84-0/Ethane
Comments/Corrections

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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