Document Detail

Competitive pathways via nonadiabatic transitions in photodissociation.
MedLine Citation:
PMID:  11513569     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Photodissociation processes of molecules and radicals involving multiple pathways and nonadiabatic crossings are studied using the photofragment imaging technique and the core-sampling version of time-of-flight spectroscopy. Capabilities and challenges are illustrated by two systems. The isocyanic acid system demonstrates how interactions among potential energy surfaces can change during dissociation. The hydroxymethyl photodecomposition system highlights Rydberg-valence interactions common in free radicals. The cross-fertilization between theory and experiment is emphasized.
D Conroy; V Aristov; L Feng; A Sanov; H Reisler
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Accounts of chemical research     Volume:  34     ISSN:  0001-4842     ISO Abbreviation:  Acc. Chem. Res.     Publication Date:  2001 Aug 
Date Detail:
Created Date:  2001-08-21     Completed Date:  2001-10-04     Revised Date:  2003-10-31    
Medline Journal Info:
Nlm Unique ID:  0157313     Medline TA:  Acc Chem Res     Country:  United States    
Other Details:
Languages:  eng     Pagination:  625-32     Citation Subset:  -    
Department of Chemistry, University of Southern California, Los Angeles, California 90089-0482, USA.
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