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Communication: A case where the hard∕soft acid∕base principle holds regardless of acid∕base strength.
MedLine Citation:
PMID:  23676022     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We show that the hard∕soft acid∕base principle holds when electron-transfer effects are dominant and the weaker acid and stronger base are harder than the other acidic and basic reagents. In this case the preference of strong acids for strong bases and weak acids for weak bases reinforces the preference of hard acids for hard bases and soft acids for soft bases.
Authors:
Paul W Ayers; Carlos Cárdenas
Publication Detail:
Type:  JOURNAL ARTICLE    
Journal Detail:
Title:  The Journal of chemical physics     Volume:  138     ISSN:  1089-7690     ISO Abbreviation:  J Chem Phys     Publication Date:  2013 May 
Date Detail:
Created Date:  2013-5-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0375360     Medline TA:  J Chem Phys     Country:  -    
Other Details:
Languages:  ENG     Pagination:  181106     Citation Subset:  -    
Affiliation:
Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Ontario L8S 4M1, Canada.
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