Document Detail

Combined Crossed Beam and Theoretical Studies of the N((2)D)+C(2)H(4) Reaction and Implications for Atmospheric Models of Titan.
MedLine Citation:
PMID:  23016665     Owner:  NLM     Status:  Publisher    
The dynamics of the H-displacement channels in the reaction N(2D) + C2H4 have been investigated by the crossed molecular beam technique with mass spectrometric detection and time-of-flight analysis at two different collision energies (17.2 and 28.2 kJ/mol). The interpretation of the scattering results is assisted by new electronic structure calculations of stationary points and product energetics for the C2H4N ground state doublet potential energy surface. RRKM statistical calculations have been performed to derive the product branching ratio under the conditions of the present experiments and of the atmosphere of Titan. Similarities and differences with respect to a recent study performed in cross beam experiments coupled to ionization via tunable VUV synchrotron radiation are discussed [Lee, S.-H. et al., Phys. Chem. Chem. Phys. 2011, 13, 8515]. Implications for the atmospheric chemistry of Titan are presented.
Nadia Balucani; Dimitrios Skouteris; Francesca Leonori; Raffaele Petrucci; Mathias Hamberg; Wolf D Geppert; Piergiorgio Casavecchia; Marzio Rosi
Related Documents :
15267965 - The diazocarbene (cnn) molecule: characterization of the x 3sigma- and a 3pi electronic...
19593395 - Electronic structure of the d bent-metallocene cp(2)vcl(2): a photoelectron and density...
15291575 - A combined computational and experimental study of polynuclear ru-tppz complexes: insig...
18956105 - Spin-orbit configuration interaction study of the ultraviolet photofragmentation of xeh+.
22371335 - A tddft investigation of bay substituted perylenediimides: absorption and intersystem c...
11178085 - Fidelity balance in quantum operations.
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-27
Journal Detail:
Title:  The journal of physical chemistry. A     Volume:  -     ISSN:  1520-5215     ISO Abbreviation:  J Phys Chem A     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-28     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9890903     Medline TA:  J Phys Chem A     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine

Previous Document:  MiR-125b orchestrates cell proliferation, differentiation and migration in neural stem/progenitor ce...
Next Document:  Analysis of transmitted drug resistance in Spain in the years 2007-2010 documents a decline in mutat...