Document Detail


Cobalt(ii) fluorophosphate frameworks.
MedLine Citation:
PMID:  23037690     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Nine new cobalt fluorophosphates frameworks have been synthesised hydrothermally in a fluoride-rich medium, through the use of CoF(3) and HPF(6) as reactants in combination with Group I/II metal hydroxides and organic cations as templating species. Products have been structurally characterised using single crystal X-ray diffraction. Reaction in fluoride-rich conditions produces chain, layer and three dimensional framework structures containing new and unusual structural features based on the linking of PO(3)F, PO(2)(OH,F)(2) and Co(O,F)(n) polyhedra (n = 5-6) including μ(2), μ(3) and μ(4) bridging fluoride. Structures exhibiting inter-layer spaces and channels frequently have these lined by terminal fluoride anions of the PO(3)F, PO(2)(OH,F)(2) and Co(O,F)(n) polyhedra.
Authors:
Jennifer A Armstrong; Edward R Williams; Mark T Weller
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-4
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-5     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Chemistry, University of Southampton, Highfield Campus, Southampton, Hampshire, SO17 1BJ, UK. mtw@soton.ac.uk.
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