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Cobalt-Mediated Synthesis of the Tricyclo[5.2.1.0(1,6)]decene Framework in Solanoeclepin A.
MedLine Citation:
PMID:  23020121     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The stereocontrolled synthesis of the highly strained, tricyclo[5.2.1.0(1,6)]decene skeleton (C) of solanoeclepin A has been achieved through two key transformations: a [2,3]-Wittig rearrangement of allylpropargyl ether (A) to propargyl alcohol (B) having a trans-fused perhydroindane framework and the formation of the cyclobutane via a cobalt-mediated Hosomi-Sakurai type cyclization of an acetylene dicobalthexacarbonyl complex.
Authors:
Kuo-Wei Tsao; Chia-Yi Cheng; Minoru Isobe
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-28
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-10-1     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, National Tsing Hua University , 101, Section 2, Kuang-Fu Road, Hsinchu 30013, Taiwan.
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