| Coassembly between the Largest and Smallest Metal Chalcogenide Supertetrahedral Clusters. | |
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MedLine Citation:
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PMID: 23421915 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Reported here is the first crystalline inorganic-organic hybrid material combining In, Ge, and Cu. The trimetallic system undergoes a nanoscale separation into small In-Ge-S supertetrahedral T2 clusters and large In-Cu-S T5 clusters, which are further assembled into a T2-T5 mixed layer. This material reveals the long-range crystallographically ordered assembly from supertetrahedral clusters with 3 orders of difference, the largest size mismatch known so far for mixed-supertetrahedral-cluster materials. Theoretical simulations were performed to probe the contribution to the band structure by the different-sized semiconducting clusters. |
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Authors:
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Le Wang; Tao Wu; Xianhui Bu; Xiang Zhao; Fan Zuo; Pingyun Feng |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-2-20 |
Journal Detail:
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Title: Inorganic chemistry Volume: - ISSN: 1520-510X ISO Abbreviation: Inorg Chem Publication Date: 2013 Feb |
Date Detail:
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Created Date: 2013-2-20 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0366543 Medline TA: Inorg Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, University of California , Riverside, California 92521, United States. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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