Document Detail

Coassembly between the Largest and Smallest Metal Chalcogenide Supertetrahedral Clusters.
MedLine Citation:
PMID:  23421915     Owner:  NLM     Status:  Publisher    
Reported here is the first crystalline inorganic-organic hybrid material combining In, Ge, and Cu. The trimetallic system undergoes a nanoscale separation into small In-Ge-S supertetrahedral T2 clusters and large In-Cu-S T5 clusters, which are further assembled into a T2-T5 mixed layer. This material reveals the long-range crystallographically ordered assembly from supertetrahedral clusters with 3 orders of difference, the largest size mismatch known so far for mixed-supertetrahedral-cluster materials. Theoretical simulations were performed to probe the contribution to the band structure by the different-sized semiconducting clusters.
Le Wang; Tao Wu; Xianhui Bu; Xiang Zhao; Fan Zuo; Pingyun Feng
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-2-20
Journal Detail:
Title:  Inorganic chemistry     Volume:  -     ISSN:  1520-510X     ISO Abbreviation:  Inorg Chem     Publication Date:  2013 Feb 
Date Detail:
Created Date:  2013-2-20     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Department of Chemistry, University of California , Riverside, California 92521, United States.
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