Document Detail


Co- and terpolyesters based on isosorbide and succinic acid for coating applications: synthesis and characterization.
MedLine Citation:
PMID:  17154469     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Co- and terpolyesters based on succinic acid and isosorbide in combination with other renewable monomers such as 2,3-butanediol, 1,3-propanediol, and citric acid were synthesized and characterized. Linear polyesters were obtained via melt polycondensation of nonactivated dicarboxylic acids with OH functional monomers. Polymer end functionality (i.e., hydroxyl or carboxylic acid) was controlled by adjusting the monomer stoichiometry. The glass transition temperatures of the resulting polyesters could be effectively adjusted by varying the polymer composition and molar mass. By adding polyfunctional monomers such as trimethylolpropane or citric acid, polyesters with enhanced functionality were obtained. These biobased polyesters displayed functionalities and Tg values in the appropriate range for (powder) coating applications. The polyesters were cross-linked using conventional curing agents. Coatings from branched polyesters--hydroxyl as well as acid functional--showed significantly improved mechanical and chemical resistance compared to those formulated from linear polymers. These renewable polyesters proved to be suitable materials for coating applications with respect to solvent resistance, impact resistance, and hardness.
Authors:
Bart A J Noordover; Viola G van Staalduinen; Robbert Duchateau; Cor E Koning; Rolf A T M van Benthem; Manon Mak; Andreas Heise; August E Frissen; Jacco van Haveren
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Biomacromolecules     Volume:  7     ISSN:  1525-7797     ISO Abbreviation:  Biomacromolecules     Publication Date:  2006 Dec 
Date Detail:
Created Date:  2006-12-12     Completed Date:  2007-02-20     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100892849     Medline TA:  Biomacromolecules     Country:  United States    
Other Details:
Languages:  eng     Pagination:  3406-16     Citation Subset:  IM    
Affiliation:
Laboratories of Polymer Chemistry and of Materials and Interface Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven, DSM Research, P.O. Box 18, 6160 MD Geleen, The Netherlands.
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MeSH Terms
Descriptor/Qualifier:
Butylene Glycols
Carboxylic Acids
Coated Materials, Biocompatible*
Isosorbide*
Kinetics
Magnetic Resonance Spectroscopy
Models, Molecular
Polyesters*
Polymers
Succinic Acid*
Chemical
Reg. No./Substance:
0/Butylene Glycols; 0/Carboxylic Acids; 0/Coated Materials, Biocompatible; 0/Polyesters; 0/Polymers; 110-15-6/Succinic Acid; 513-85-9/2,3-butylene glycol; 652-67-5/Isosorbide

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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