| Resolution/deracemization of chiral alpha-amino acids using resolving reagents with flexible stereogenic centers. | |
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MedLine Citation:
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PMID: 19422236 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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This work has demonstrated that a previously unexplored approach to separation of enantiomers via formation of diastereomeric derivatives with three stereogenic centers has obvious practical potential and deserves further systematic study. The design reported here is based on the unusual application of a configurationally unstable stereogenic nitrogen, which plays a key role in setting up the stereochemical match between the three stereogenic centers in the corresponding products. |
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Authors:
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Vadim A Soloshonok; Trevor K Ellis; Hisanori Ueki; Taizo Ono |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: 131 ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2009 Jun |
Date Detail:
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Created Date: 2009-05-27 Completed Date: 2009-07-31 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: United States |
Other Details:
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Languages: eng Pagination: 7208-9 Citation Subset: IM |
Affiliation:
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Department of Chemistry and Biochemistry, University of Oklahoma, Norman, Oklahoma 73019, USA. vadim@ou.edu |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Amino Acids
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chemistry,
isolation & purification* Indicators and Reagents Optical Rotation Stereoisomerism |
| Chemical | |
Reg. No./Substance:
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0/Amino Acids; 0/Indicators and Reagents |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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