Document Detail

Chiral BINOL-derived phosphoric acids: privileged Brønsted acid organocatalysts for C-C bond formation reactions.
MedLine Citation:
PMID:  20820680     Owner:  NLM     Status:  MEDLINE    
BINOL-derived phosphoric acids have emerged during the last five years as powerful chiral Brønsted acid catalysts in many enantioselective processes. The most successful transformations carried out with chiral BINOL phosphates include C-C bond formation reactions. The recent advances have been reviewed in this article with a focus being placed on hydrocyanations, aldol-type, Mannich, Friedel-Crafts, aza-ene-type, Diels-Alder, as well as cascade and multi-component reactions.
Alexandru Zamfir; Sebastian Schenker; Matthias Freund; Svetlana B Tsogoeva
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't; Review     Date:  2010-09-06
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  8     ISSN:  1477-0539     ISO Abbreviation:  Org. Biomol. Chem.     Publication Date:  2010 Dec 
Date Detail:
Created Date:  2010-11-10     Completed Date:  2011-02-01     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  England    
Other Details:
Languages:  eng     Pagination:  5262-76     Citation Subset:  IM    
Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Henkestrasse 42, 91054 Erlangen, Germany.
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MeSH Terms
Acids / chemistry*
Carbon / chemistry*
Naphthalenes / chemistry*
Phosphoric Acids / chemistry*
Reg. No./Substance:
0/Acids; 0/Naphthalenes; 0/Phosphoric Acids; 0/S(-)2,2'-dihydroxy-1,1'-binaphthyl; 7440-44-0/Carbon

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