Document Detail


Chemoselective ligation of sulfinic acids with aryl-nitroso compounds.
MedLine Citation:
PMID:  22644884     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Making a comeback: The inefficient condensation of sulfinic acid and aryl nitroso compounds has been transformed into a chemoselective process that converts sulfinic acid into stable cyclic sulfonamide analogues (see scheme). This ligation proceeds rapidly under aqueous conditions in high yield, and lays the groundwork for the development of sulfinic acid detection methods in biological systems.
Authors:
Mauro Lo Conte; Kate S Carroll
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2012-05-29
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  51     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Jun 
Date Detail:
Created Date:  2012-06-21     Completed Date:  2012-11-05     Revised Date:  2013-06-25    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  6502-5     Citation Subset:  IM    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Chemistry, The Scripps Research Institute, 130 Scripps Way, Jupiter, FL 33458, USA.
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MeSH Terms
Descriptor/Qualifier:
Molecular Structure
Nitroso Compounds / chemistry*
Sulfinic Acids / chemistry*
Grant Support
ID/Acronym/Agency:
R01 GM102187/GM/NIGMS NIH HHS
Chemical
Reg. No./Substance:
0/Nitroso Compounds; 0/Sulfinic Acids
Comments/Corrections

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