| Chemoselective ligation of sulfinic acids with aryl-nitroso compounds. | |
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MedLine Citation:
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PMID: 22644884 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Making a comeback: The inefficient condensation of sulfinic acid and aryl nitroso compounds has been transformed into a chemoselective process that converts sulfinic acid into stable cyclic sulfonamide analogues (see scheme). This ligation proceeds rapidly under aqueous conditions in high yield, and lays the groundwork for the development of sulfinic acid detection methods in biological systems. |
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Authors:
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Mauro Lo Conte; Kate S Carroll |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't Date: 2012-05-29 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: 51 ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Jun |
Date Detail:
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Created Date: 2012-06-21 Completed Date: 2012-11-05 Revised Date: 2013-04-16 |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: Germany |
Other Details:
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Languages: eng Pagination: 6502-5 Citation Subset: IM |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Department of Chemistry, The Scripps Research Institute, 130 Scripps Way, Jupiter, FL 33458, USA. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Molecular Structure Nitroso Compounds / chemistry* Sulfinic Acids / chemistry* |
| Grant Support | |
ID/Acronym/Agency:
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R01 GM102187/GM/NIGMS NIH HHS |
| Chemical | |
Reg. No./Substance:
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0/Nitroso Compounds; 0/Sulfinic Acids |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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