Document Detail

Chemiluminescence determination of tetracyclines using Fenton system in the presence europium(III) ions.
MedLine Citation:
PMID:  19345765     Owner:  NLM     Status:  MEDLINE    
A new simple chemiluminescent method for the determination of chlortetracycline (Chlor-TC), oxytetracycline (Oxy-TC) and doxycycline (Doxy-TC) is described. This method is based on the europium(III) emission as a result of the energy transfer process from the excited product of the tetracyclines oxidation to the uncomplexed Eu(III). Under the optimum conditions, calibration graphs were obtained for 4x10(-7) to 2x10(-5) mol L(-1) of Chlor-TC; 2x10(-7) to 2x10(-5) mol L(-1) of Oxy-TC and 1x10(-7) to 3x10(-5) mol L(-1) of Doxy-TC. The method was successfully applied to the determination of these drugs in pharmaceutical and veterinary formulation and honey.
Malgorzata Kaczmarek; Stefan Lis
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Publication Detail:
Type:  Journal Article     Date:  2009-03-09
Journal Detail:
Title:  Analytica chimica acta     Volume:  639     ISSN:  1873-4324     ISO Abbreviation:  Anal. Chim. Acta     Publication Date:  2009 Apr 
Date Detail:
Created Date:  2009-04-06     Completed Date:  2009-07-02     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370534     Medline TA:  Anal Chim Acta     Country:  Netherlands    
Other Details:
Languages:  eng     Pagination:  96-100     Citation Subset:  IM    
Department of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60 - 780 Poznań, Poland.
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MeSH Terms
Europium / chemistry*
Honey / analysis
Hydrogen Peroxide / chemistry*
Iron / chemistry*
Luminescent Measurements / methods*
Pharmaceutical Preparations / chemistry
Tetracyclines / analysis*,  chemistry
Water / chemistry
Reg. No./Substance:
0/Fenton's reagent; 0/Pharmaceutical Preparations; 0/Tetracyclines; 7439-89-6/Iron; 7440-53-1/Europium; 7722-84-1/Hydrogen Peroxide; 7732-18-5/Water

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